4-(2,4,6-trinitroanilino)benzoic acid (p-picraminobenzoic acid), C13H8N3O8, obtained by the reaction of 2,4,6-trinitrobenzenesulfonic acid (picrylsulfonic acid) with 4-aminobenzoic acid in 2-propanol-water, forms a two-dimensional hydrogen-bonded network based on centrosymmetric cyclic R2/2(8) carboxylic acid dimers which are extended through lateral N-H...O(carboxyl) interactions. The amino group also makes an intramoleclar N-H...O(nitro) hydrogen bond, while the two aromatic ring systems are, as expected, non-coplanar, the C-C-N-C torsion angles being 152.0(2)(picryl) and 136.1(2)deg. (benzoic acid).
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|Item Type:||Journal Article|
|Keywords:||4, (2, 4, 6, trinitroanilino)benzoic acid, crystal structure|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606)|
|Divisions:||Past > QUT Faculties & Divisions > Faculty of Science and Technology|
|Copyright Owner:||Copyright 2007 International Union of Crystallography|
|Copyright Statement:||Reproduced in accordance with the copyright policy of the publisher.|
|Deposited On:||26 Nov 2007|
|Last Modified:||29 Feb 2012 23:39|
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