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The 1:1 adduct of Kemp's triacid with 2-aminopyridine

Smith, Graham, Bott, Raymond C., & Wermuth, Urs D. (2000) The 1:1 adduct of Kemp's triacid with 2-aminopyridine. Acta Crystallographica. Section C: Crystal Structure Communications, C56(12), pp. 1505-1506.

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Abstract

The crystal structure determination of the molecular proton-transfer adduct of Kemp's triacid (cis-cis-1,3,5-trimethylcyclohexane-1,3,5-tricarboxylic acid, KTA) with 2-aminopyridine (2-APY), namely 2-aminopyridinium 3,5-dicarboxy-1,3,5-trimethylcyclohexanecarboxylate, 2-APY+·KTA- or C5H7N2+·C12H17O6-, has revealed a centrosymmetric hydrogen-bonded cyclic KTA homodimer repeating unit [OO 2.524 (4) Å] linked into a polymer structure through the pyridinium and amino groups of the 2-APY molecule [ON 2.736 (4), 2.989 (4) and 2.999 (4) Å].

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ID Code: 13137
Item Type: Journal Article
DOI: 10.1107/S0108270100012968
ISSN: 0108-2701
Divisions: Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright 2000 International Union of Crystallography (IUCr)
Copyright Statement: Reproduced in accordance with the copyright policy of the publisher.
Deposited On: 25 Mar 2008
Last Modified: 09 Jun 2010 22:57

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