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Edge-Modification of Laponite with Dimethyl-octylmethoxysilane

Frost, Ray L., Daniel, Lisa M., & Zhu, Huai Yong (2008) Edge-Modification of Laponite with Dimethyl-octylmethoxysilane. Journal of Colloid and Interface Science, 321(2), pp. 302-309.

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Abstract

This study examines the edge modification of laponite, with a monoalkoxy silane, dimethyloctyl methoxysilane. The influence of ultrasonics, aging time and silane concentration on the resultant materials is examined. The silylated clays are characterized by XRD, IES, TGA, and Si-NMR. The amount of grafted silane was increased by increasing the ratio of silane to clay, sonication of the reaction mixture and ageing the reaction mixture for no more than 24 hours to avoid removal of grafted silane due to equilibrium effects.

Impact and interest:

24 citations in Scopus
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21 citations in Web of Science®

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477 since deposited on 16 Apr 2008
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ID Code: 13325
Item Type: Journal Article
Keywords: laponite, silane, silylation, edge, modification, IES
DOI: 10.1016/j.jcis.2008.01.032
ISSN: 0021-9797
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600)
Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Catalysis and Mechanisms of Reactions (030601)
Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Colloid and Surface Chemistry (030603)
Divisions: Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright 2008 Elsevier
Copyright Statement: Reproduced in accordance with the copyright policy of the publisher.
Deposited On: 16 Apr 2008
Last Modified: 25 Feb 2013 12:47

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