Synthesis of dianionic and trianionic chiral, chelating ligands based on amino acids
Schultz, Madeleine, Kulis, Jakov, Murison, Julie, & Andrews, Genevieve W. (2008) Synthesis of dianionic and trianionic chiral, chelating ligands based on amino acids. Australian Journal of Chemistry, 61(4), pp. 297-302.
The synthesis of two new families of amino acid-containing chiral ligands, based on methyliminodiacetic acid and nitrilotriacetic acid cores, has been accomplished using a simple protection, solution phase amide coupling and deprotection strategy. The amino acids glycine, leucine, aspartic acid and phenylalanine were used to demonstrate the versatility of the synthetic route, and that no epimerisation occurs. Thus, the tridentate ligands bear C3 symmetry, while the bidentate ligands have C1 symmetry.
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|Item Type:||Journal Article|
|Keywords:||chiral chelating ligands, amino acids|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > INORGANIC CHEMISTRY (030200) > Transition Metal Chemistry (030207)|
Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > ORGANIC CHEMISTRY (030500) > Organic Chemical Synthesis (030503)
|Divisions:||Past > QUT Faculties & Divisions > Faculty of Science and Technology|
|Copyright Owner:||Copyright 2008 CSIRO Publishing|
|Copyright Statement:||Reproduced in accordance with the copyright policy of the publisher.|
|Deposited On:||01 May 2008|
|Last Modified:||29 Feb 2012 23:48|
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