Raman spectroscopic study of the uranyl mineral compreignacite K2[(UO2)3O2(OH)3]2.7H2O
Raman spectra of the uranyl oxyhydroxy hydrated mineral compreignacite, K2[(UO2)3O2(OH)3]2.7H2O, were measured and interpreted. Observed bands were attributed to the stretching and bending vibrations of uranyl units, molecular water and hydroxyl ions. U-O bond lengths in uranyl and O-H…O hydrogen bond lengths were inferred from the spectra and compared with those from the X-ray single crystal structure data. The importance of this spectroscopic study rests with the ability to analyze very small amounts of mineral.
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|Item Type:||Journal Article|
|Keywords:||compreignacite, uranyl oxyhydroxy hydrates, uranyl, Raman spectroscopy, infrared spectroscopy, U, O bond lengths, hydrogen bonds|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600)|
Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606)
Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Colloid and Surface Chemistry (030603)
|Divisions:||Past > QUT Faculties & Divisions > Faculty of Science and Technology|
Past > Schools > School of Physical & Chemical Sciences
|Copyright Owner:||Copyright 2008 John Wiley & Sons|
|Copyright Statement:||The definitive version is available on publication at www3.interscience.wiley.com|
|Deposited On:||28 Aug 2008|
|Last Modified:||29 Feb 2012 23:50|
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