Conformation of surfactant molecules in the interlayer of montmorillonite studied by 13C MAS NMR
He, Hongping, Frost, Ray L., Deng, Feng , Zhu, Jianxi , Wen, Xiaoyan, & Yuan, Peng (2004) Conformation of surfactant molecules in the interlayer of montmorillonite studied by 13C MAS NMR. Clays and Clay Minerals, 52(3), pp. 350-356.
The ordering conformation of surfactant molecules in intercalated montmorillonite prepared at various concentrations has been investigated by 13C MAS NMR. The 13C MAS NMR study demonstrates the coexistence of ordered and disordered chain conformations. Two main resonance peaks are associated with the backbone alkyl chains: the resonance at 33 ppm corresponds to the ordered conformation (all-trans), and the resonance at 30 ppm corresponds to the disordered conformation (mixture of trans and gauche). The deconvolution of 13C MAS NMR spectra indicates that the ordering conformation of surfactant molecules within the gallery of montmorillonite strongly depends on their orientation and packing density. When amine chains have orientation parallel to the silicate layers, the amount of all-trans conformer decreases with the increase of amine concentration. However, the amount of all-trans conformer increases with the increase of amine concentration when amine chains radiate from the silicate layers. Furthermore, 13C MAS NMR spectra show that the intercalated surfactant molecules in the clay minerals never attained the complete liquidlike or solidlike behaviour.
Impact and interest:
Citation countsare sourced monthly fromand citation databases.
These databases contain citations from different subsets of available publications and different time periods and thus the citation count from each is usually different. Some works are not in either database and no count is displayed. Scopus includes citations from articles published in 1996 onwards, and Web of Science® generally from 1980 onwards.
Citations counts from theindexing service can be viewed at the linked Google Scholar™ search.
Full-text downloadsdisplays the total number of times this work’s files (e.g., a PDF) have been downloaded from QUT ePrints as well as the number of downloads in the previous 365 days. The count includes downloads for all files if a work has more than one.
|Item Type:||Journal Article|
|Additional Information:||Self-archiving of the author-version is not yet supported by this publisher. For more information, please refer to the journal's website (see link) or contact the author. Ray Frost: firstname.lastname@example.org or Hongping He: email@example.com|
|Keywords:||Conformation, Surfactant, Montmorillonite, 13C MAS NMR|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > INORGANIC CHEMISTRY (030200)|
|Divisions:||Past > QUT Faculties & Divisions > Faculty of Science and Technology|
|Copyright Owner:||Copyright 2004 Clay Minerals Society|
|Deposited On:||18 Oct 2005|
|Last Modified:||02 Mar 2012 12:10|
Repository Staff Only: item control page