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Fourier Transform Ion Cyclotron Resonance Studies of Gas-Phase Reactions Between Tungsten Ions and Hydrocarbons

Kikhtenko, Andrey V., Goncharov, Vladimir B., Momot, Konstantin I., & Zamaraev, Kirill I. (1994) Fourier Transform Ion Cyclotron Resonance Studies of Gas-Phase Reactions Between Tungsten Ions and Hydrocarbons. Organometallics, 13(6), pp. 2536-2538.

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Abstract

Summary: FT ICR spectrometry has been used for gas-phase studies of the interaction between singly-charged positive tungsten ions and hydrocarbons (alkanes C2-C9, alkenes C2-C6, and cycloalkanes C3-C6). It is shown that this interaction results mainly in dehydrogenation products. The number of H2 molecules eliminated depends upon the size and type of hydrocarbon and varies from 1 to 6. Significant amounts of C-C cleavage products have been found in the cases of cyclopropane and 2-methylpropene only.

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12 citations in Web of Science®

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ID Code: 15679
Item Type: Journal Article
Additional Information: This article is freely available from the American Chemical Society website 12 months after the publication date. See links to publisher website in this record.
DOI: 10.1021/om00018a060
ISSN: 1520-6041
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Catalysis and Mechanisms of Reactions (030601)
Divisions: Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright 1994 American Chemical Society
Deposited On: 21 Nov 2008
Last Modified: 09 Mar 2011 11:58

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