Fourier Transform Ion Cyclotron Resonance Studies of Gas-Phase Reactions Between Tungsten Ions and Hydrocarbons
Kikhtenko, Andrey V., Goncharov, Vladimir B., Momot, Konstantin I., & Zamaraev, Kirill I. (1994) Fourier Transform Ion Cyclotron Resonance Studies of Gas-Phase Reactions Between Tungsten Ions and Hydrocarbons. Organometallics, 13(6), pp. 2536-2538.
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Summary: FT ICR spectrometry has been used for gas-phase studies of the interaction between singly-charged positive tungsten ions and hydrocarbons (alkanes C2-C9, alkenes C2-C6, and cycloalkanes C3-C6). It is shown that this interaction results mainly in dehydrogenation products. The number of H2 molecules eliminated depends upon the size and type of hydrocarbon and varies from 1 to 6. Significant amounts of C-C cleavage products have been found in the cases of cyclopropane and 2-methylpropene only.
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|Item Type:||Journal Article|
|Additional Information:||This article is freely available from the American Chemical Society website 12 months after the publication date. See links to publisher website in this record.|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Catalysis and Mechanisms of Reactions (030601)|
|Divisions:||Past > QUT Faculties & Divisions > Faculty of Science and Technology|
|Copyright Owner:||Copyright 1994 American Chemical Society|
|Deposited On:||21 Nov 2008|
|Last Modified:||09 Mar 2011 11:58|
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