Raman spectroscopic study of the uranyl tellurite mineral moctezumite PbUO2(TeO3)2
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The uranyl tellurite mineral moctezumite, Pb(UO2)(TeO3)2 was studied by Raman spectroscopy, complemented with infrared spectroscopy. The presence of the stretching and bending vibrations of uranyl, (UO2)2+, and tellurite, (TeO3)2-, ions was inferred and observed bands were assigned to uranyl and tellurite units vibrations. U-O bond lengths calculated from the spectra with two empirical relations are close to those inferred from the X-ray single crystal structure of moctezumite.
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|Item Type:||Journal Article|
|Additional Information:||Self-archiving of the author-version in institutional repositories is not currently supported by this publisher. For more information, please refer to the journal's website (see hypertext link) or contact the author.|
|Keywords:||moctezumite, uranyl tellurite, Raman spectroscopy, infrared spectroscopy, U-O bond length|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606)|
|Divisions:||Past > QUT Faculties & Divisions > Faculty of Science and Technology|
Past > Schools > School of Physical & Chemical Sciences
|Copyright Owner:||Copyright 2009 John Wiley and Sons|
|Deposited On:||02 Feb 2009 12:08|
|Last Modified:||01 Mar 2012 00:02|
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