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Modified porphyrinoids from carbazates and hydrazones and the first crystal structure of a di-iminoporphodimethene

Esdaile, Louisa J., McMurtrie, John C., Turner, Peter., & Arnold, Dennis P. (2005) Modified porphyrinoids from carbazates and hydrazones and the first crystal structure of a di-iminoporphodimethene. Tetrahedron Letters, 46(40), pp. 6931-6935.

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Abstract

Novel porphyrinoids with interrupted conjugation (di-iminoporphodimethenes) result from the Pd-catalyzed coupling of meso-bromo porphyrins and their metal complexes with carbazates and hydrazones, followed by aerial oxidation. X-Ray crystallography revealed a saddle shape for molecules of the nickel(II) complex of a di-iminoporphodimethene.

Impact and interest:

15 citations in Scopus
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15 citations in Web of Science®

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505 since deposited on 04 Aug 2005
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ID Code: 1937
Item Type: Journal Article
Keywords: porphyrins, carbazate, porphodimethene, crystal structure
DOI: 10.1016/j.tetlet.2005.08.004
ISSN: 0040-4039
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > ORGANIC CHEMISTRY (030500)
Divisions: Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright 2005 Elsevier
Copyright Statement: Reproduced in accordance with the copyright policy of the publisher.
Deposited On: 04 Aug 2005
Last Modified: 29 Feb 2012 23:15

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