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Raman spectroscopic study of the uranyl selenite mineral demesmaekerite Pb2Cu5(UO2)2(SeO3)6(OH)6.2H2O

Frost, Ray L., Cejka, Jiri, & Dickfos, Marilla J. (2009) Raman spectroscopic study of the uranyl selenite mineral demesmaekerite Pb2Cu5(UO2)2(SeO3)6(OH)6.2H2O. Journal of Raman Spectroscopy, 40(5).

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Abstract

The Raman spectrum of uranyl selenite mineral demesmaekerite was studied, complemented by infrared spectrum, and tentatively interpreted. Stretching and bending vibrations of (UO2)2+, (SeO3)2- and OH groupings were attributed to observed bands. U-O bond lengths in uranyl and O-H…O hydrogen bond lengths were calculated from Raman and/or infrared spectra and compared with published data.

Impact and interest:

10 citations in Scopus
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10 citations in Web of Science®

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ID Code: 20413
Item Type: Journal Article
Additional URLs:
Keywords: demesmaekerite, uranyl selenite, Raman spectroscopy, U-O bond length, O-H…O bond lengths
DOI: 10.1002/jrs.2074
ISSN: 0377-0486
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Physical Chemistry not elsewhere classified (030699)
Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606)
Divisions: Past > QUT Faculties & Divisions > Faculty of Science and Technology
Past > Schools > School of Physical & Chemical Sciences
Copyright Owner: Copyright 2009 John Wiley & Sons
Deposited On: 12 May 2009 15:42
Last Modified: 01 Mar 2012 00:02

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