DSC and high-resolution TG of synthesized hydrotalcites of Mg and Zn
Frost, Ray L., Martens, Wayde N., Ding, Zhe, & Kloprogge, J. Theo (2003) DSC and high-resolution TG of synthesized hydrotalcites of Mg and Zn. Journal of Thermal Analysis and Calorimetry, 71(2), pp. 429-438.
A combination of DSC and high resolution DTG coupled to a gas evolution mass spectrometer has been used to study the thermal properties of a series of Mg/Zn hydrotalcites of formulae MgxZn6-xAl2(OH)16(CO3) ·4H2O where x varied from 6 to 0. The effect of increased Zn composition results in the decrease of the endotherms and mass loss steps to lower temperatures. Evolved gas mass spectrometry shows that water is lost in a number of steps. The interlayer carbonate anion is lost simultaneously with hydroxyl units.
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|Item Type:||Journal Article|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600)|
|Divisions:||Past > QUT Faculties & Divisions > Faculty of Science and Technology|
|Copyright Owner:||Copyright 2003 Akademiai Kiado Rt. (Springer)|
|Deposited On:||17 Jun 2009 13:04|
|Last Modified:||01 Mar 2012 18:34|
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