Raman spectroscopy of lead sulphate-carbonate minerals: implications for hydrogen bonding
Frost, Ray L., Kloprogge, J. Theo, & Williams, Peter (2003) Raman spectroscopy of lead sulphate-carbonate minerals: implications for hydrogen bonding. Neues Jahrbuch fuer Mineralogie. Monatshefte, 2003(12), pp. 529-542.
The Raman spectrum of the basic carbonate-sulphate minerals known as leadhillite, susannite and caledonite have been measured and the spectra compared with the Raman spectra of cerussite, hydrocerussite and anglesite. Characteristic spectral patterns are observed for each mineral. The wavenumber position of the hydroxyl stretching bands is used to estimate the hydrogen bond distances in the minerals. The hydrogen bond distances for leadhillite polymorphs vary from 2.783 to 2.916 Å. In comparison the estimated hydrogen bond distances for hydrocerussite are much longer with values of 2.961 and 3.127 Å. The width of the hydroxyl stretching vibration provides an estimate of the variation of hydrogen bond distances for the OH groups in the mineral. The variation in bond length is greater for the longer hydrogen bonds. Characteristic sulphate and carbonate vibrations are also identified.
Impact and interest:
Citation counts are sourced monthly from and citation databases.
These databases contain citations from different subsets of available publications and different time periods and thus the citation count from each is usually different. Some works are not in either database and no count is displayed. Scopus includes citations from articles published in 1996 onwards, and Web of Science® generally from 1980 onwards.
Citations counts from theindexing service can be viewed at the linked Google Scholar™ search.
Full-text downloads displays the total number of times this work’s files (e.g., a PDF) have been downloaded from QUT ePrints as well as the number of downloads in the previous 365 days. The count includes downloads for all files if a work has more than one.
|Item Type:||Journal Article|
|Divisions:||Past > QUT Faculties & Divisions > Faculty of Science and Technology|
|Copyright Owner:||Copyright 2003 E. Schweizerbart'sche Verlagsbuchhandlung|
|Deposited On:||17 Jun 2009 13:06|
|Last Modified:||29 Feb 2012 17:13|
Repository Staff Only: item control page