An infrared spectroscopic study of the basic copper phosphate minerals: Cornetite, libethenite, and pseudomalachite

Martens, Wayde N. & Frost, Ray L. (2003) An infrared spectroscopic study of the basic copper phosphate minerals: Cornetite, libethenite, and pseudomalachite. American Mineralogist, 88(1), pp. 37-46.

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The molecular structures of the basic copper phosphate minerals pseudomalachite, libethenite, and cornetite were studied using a combination of infrared emission spectroscopy, infrared absorption, and Raman spectroscopy. Infrared emission spectra of these minerals were obtained over the temperature range 100 to 1000 °C.

The infrared spectra of the three minerals are different, in line with differences in crystal structure and composition. The absorption spectra are similar, particularly in the OH stretching region, but characteristic differences in the bending regions are observed. Differences are also observed in the phosphate stretching and bending regions. The IR emission of the basic copper phosphates studied shows that the minerals are completely dehydroxylated by 550 °C.

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33 citations in Scopus
34 citations in Web of Science®
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ID Code: 22374
Item Type: Journal Article
Refereed: Yes
Additional URLs:
ISSN: 0003-004X
Subjects: Australian and New Zealand Standard Research Classification > EARTH SCIENCES (040000) > GEOLOGY (040300)
Divisions: Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright 2003 Mineralogical Society of America
Deposited On: 17 Jun 2009 13:11
Last Modified: 02 Mar 2012 11:56

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