Slow transformation of mechanically dehydroxylated kaolinite to kaolinite—an aged mechanochemically activated formamide-intercalated kaolinite study
Frost, Ray L., Horvath, Erzsebet, Mako, Eva, Kristof, Janos, & Redey, Akos (2003) Slow transformation of mechanically dehydroxylated kaolinite to kaolinite—an aged mechanochemically activated formamide-intercalated kaolinite study. Thermochimica Acta, 408(1-2), pp. 103-113.
Formamide-intercalated high defect kaolinite which was mechanochemically activated for periods of time up to 6 h has been aged for up to 1 year. These modified materials were studied using a combination of X-ray diffraction, thermal analysis and DRIFT spectroscopy. Ageing of the formamide-intercalated mechanochemically activated kaolinite results in de-intercalation of the formamide and the de-intercalated kaolinite returns to its original d-spacing. Thermal analysis shows that the temperature of dehydration and dehydroxylation increase by up to 30 °C. The temperature of the dehydroxylation of the aged samples was identical to that of the untreated kaolinite. The DRIFT spectroscopy showed that the spectrum of the aged samples approached that of the untreated kaolinite. The kaolinite showed partial de-intercalation and the 6 h sample had reformed to a mineral resembling the untreated kaolinite. The process of ageing the mechanochemically activated kaolinite enabled the reformation of the kaolinite.
Citation countsare sourced monthly fromand citation databases.
These databases contain citations from different subsets of available publications and different time periods and thus the citation count from each is usually different. Some works are not in either database and no count is displayed. Scopus includes citations from articles published in 1996 onwards, and Web of Science® generally from 1980 onwards.
Citations counts from theindexing service can be viewed at the linked Google Scholar™ search.
Full-text downloadsdisplays the total number of times this work’s files (e.g., a PDF) have been downloaded from QUT ePrints as well as the number of downloads in the previous 365 days. The count includes downloads for all files if a work has more than one.
|Item Type:||Journal Article|
|Keywords:||Kaolinite, Mechanochemical activation, Differential thermogravimetric analysis|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > ANALYTICAL CHEMISTRY (030100)|
|Divisions:||Past > QUT Faculties & Divisions > Faculty of Science and Technology|
|Copyright Owner:||Copyright 2003 Elsevier|
|Deposited On:||17 Jun 2009 23:25|
|Last Modified:||01 Mar 2012 19:15|
Repository Staff Only: item control page