Peripherally η1-Platinated Organometallic Porphyrins as Building Blocks for Multiporphyrin Arrays

Arnold, Dennis & Hartnell, Regan (2004) Peripherally η1-Platinated Organometallic Porphyrins as Building Blocks for Multiporphyrin Arrays. Organometallics, 23(3), pp. 391-399.

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The modification of peripherally metalated meso-η1-platiniometalloporphyrins, such as trans-[PtBr(NiDAPP)(PPh3)2] (H2DAPP = 5-phenyl-10,20-bis(3‘,5‘-di-tert-butylphenyl)porphyrin), leads to the analogous platinum(II) nitrato and triflato electrophiles in almost quantitative yields. Self-assembly reactions of these meso-platinioporphyrin tectons with pyridine, 4,4‘-bipyridine, or various meso-4-pyridylporphyrins in chloroform generate new multicomponent organometallic porphyrin arrays containing up to five porphyrin units. These new types of supramolecular arrays are formed exclusively in high yields and are stable in solution or in the solid state for extended periods. They were characterized by multinuclear NMR and UV−visible spectroscopy as well as high-resolution electrospray ionization mass spectrometry.

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ID Code: 23429
Item Type: Journal Article
Refereed: Yes
Additional Information: This article is freely available from the American Chemical Society website 12 months after the publication date. See the DOI link to publisher's website in this record.
DOI: 10.1021/om0305869
ISSN: 0276-7333
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > OTHER CHEMICAL SCIENCES (039900)
Divisions: Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright 2004 American Chemical Society
Deposited On: 17 Jun 2009 13:54
Last Modified: 29 Feb 2012 13:04

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