Sodium 2-nitrocinnamate dihydrate: a one-dimensional hydrogen-bonded coordination polymer
The title compound catena-poly[aqua-mu3-2-nitrocinnamato],
[Na(C9H6NO4)(H2O)2]n, the sodium salt of trans-2-nitrocinnamic acid, is a one-dimensional coordination polymer based on six-coordinate octahedral NaO6 centres comprising three facially-related monodentate carboxylate O-atom donors from separate ligands (all bridging)[Na-O, 2.4370(13)-2.5046(13)A] and three water molecules
(two bridging, one monodentate) [Na-O, 2.3782(13)-2.4404(17)A]. The structure is also stabilized by intra-chain
water-O-H...O(carboxylate) and O-H...O(nitro) hydrogen bonds.
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|Item Type:||Journal Article|
|Keywords:||crystal structure , coordination polymer, trans-2-nitrocinnamic acid, hydrogen bonding|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606)|
|Divisions:||Past > QUT Faculties & Divisions > Faculty of Science and Technology|
Past > Schools > School of Physical & Chemical Sciences
|Copyright Owner:||Copyright 2009 Blackwell Publishing and the authors.|
|Copyright Statement:||The definitive version is available at www.blackwell-synergy.com|
|Deposited On:||12 Oct 2009 08:39|
|Last Modified:||01 Mar 2012 00:09|
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