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Sodium 2-nitrocinnamate dihydrate: a one-dimensional hydrogen-bonded coordination polymer

Smith, Graham & Wermuth, Urs D. (2009) Sodium 2-nitrocinnamate dihydrate: a one-dimensional hydrogen-bonded coordination polymer. Acta Crystallographica Section E, 65, m1048.

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Abstract

The title compound catena-poly[aqua-mu3-2-nitrocinnamato], [Na(C9H6NO4)(H2O)2]n, the sodium salt of trans-2-nitrocinnamic acid, is a one-dimensional coordination polymer based on six-coordinate octahedral NaO6 centres comprising three facially-related monodentate carboxylate O-atom donors from separate ligands (all bridging)[Na-O, 2.4370(13)-2.5046(13)A] and three water molecules (two bridging, one monodentate) [Na-O, 2.3782(13)-2.4404(17)A]. The structure is also stabilized by intra-chain water-O-H...O(carboxylate) and O-H...O(nitro) hydrogen bonds.

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ID Code: 27836
Item Type: Journal Article
Keywords: crystal structure , coordination polymer, trans-2-nitrocinnamic acid, hydrogen bonding
DOI: 10.1107/S1600536809030402
ISSN: 1600-5368
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606)
Divisions: Past > QUT Faculties & Divisions > Faculty of Science and Technology
Past > Schools > School of Physical & Chemical Sciences
Copyright Owner: Copyright 2009 Blackwell Publishing and the authors.
Copyright Statement: The definitive version is available at www.blackwell-synergy.com
Deposited On: 12 Oct 2009 08:39
Last Modified: 01 Mar 2012 00:09

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