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Raman spectroscopic study of the uranyl mineral natrouranospinite (Na2,Ca)[(UO2)(AsO4)]2•5H2O

Frost, Ray L., Cejka, Jiri, Keeffe, Eloise C., & Sejkora, Jiri (2009) Raman spectroscopic study of the uranyl mineral natrouranospinite (Na2,Ca)[(UO2)(AsO4)]2•5H2O. Journal of Raman Spectroscopy, 40(11), pp. 1521-1526.

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Abstract

Raman spectra of natrouranospinite complemented with infrared spectra were studied and related to the structure of the mineral. Observed bands were assigned to the stretching and bending vibrations of (UO2)2+ and (AsO4)3- units and of water molecules. U-O bond lengths in uranyl and O-H…O hydrogen bond lengths were calculated from the Raman and infrared spectra.

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ID Code: 28594
Item Type: Journal Article
Additional Information: This paper is one of a series on the Raman spectroscopy of uranyl arsenates
Keywords: natrouranopinite, mineral, , Raman, , uranyl, arsenate, , infrared, spectroscopy, molecular water,
DOI: 10.1002/jrs.2233
ISSN: 0377-0486
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Colloid and Surface Chemistry (030603)
Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600)
Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606)
Divisions: Past > QUT Faculties & Divisions > Faculty of Science and Technology
Past > Schools > School of Physical & Chemical Sciences
Copyright Owner: Copyright © 2009 John Wiley & Sons, Ltd.
Copyright Statement: The definitive version is available at www3.interscience.wiley.com
Deposited On: 12 Nov 2009 15:48
Last Modified: 01 Mar 2012 00:07

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