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Raman spectroscopic study of the uranyl sulphate mineral jáchymovite (UO2)8(SO4)(OH)14•13H2O

Frost, Ray L., Cejka, Jiri, Keeffe, Eloise C., & Sejkora, Jiri (2009) Raman spectroscopic study of the uranyl sulphate mineral jáchymovite (UO2)8(SO4)(OH)14•13H2O. Journal of Raman Spectroscopy, 40(11), pp. 1464-1468.

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Abstract

Raman spectra of jáchymovite, (UO2)8(SO4)(OH)14•13H2O, were studied, complemented with infrared spectra, and compared with published Raman and infrared spectra of uranopilite, [(UO2)6(SO4)O2(OH)6(H2O)6] •6H2O. Bands related to the stretching and bending vibrations of (UO2)2+, (SO4)2-, (OH)- and water molecules were assigned. U-O bond lengths in uranyl and O-H…O hydrogen bond lengths were calculated from the Raman and infrared spectra.

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ID Code: 28595
Item Type: Journal Article
Additional Information: This paper is one of a series of papers on the Raman spectroscopy of secondary minerals
Keywords: jáchymovite, uranyl, sulphate, , U-O bond lengths,, O-H…O hydrogen bond lengths, Raman spectroscopy, , infrared spectroscopy,
DOI: 10.1002/jrs.2227
ISSN: 0377-0486
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Colloid and Surface Chemistry (030603)
Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600)
Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606)
Divisions: Past > QUT Faculties & Divisions > Faculty of Science and Technology
Past > Schools > School of Physical & Chemical Sciences
Copyright Owner: Copyright © 2009 John Wiley & Sons, Ltd.
Copyright Statement: The definitive version is available at www3.interscience.wiley.com
Deposited On: 12 Nov 2009 16:01
Last Modified: 01 Mar 2012 00:07

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