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Raman spectroscopic study of the uranyl mineral metauranospinite Ca[(UO2)(AsO4)]2.8H2O

Frost, Ray L., Keeffe, Eloise C., Cejka, Jiri, & Sejkora, Jiri (2009) Raman spectroscopic study of the uranyl mineral metauranospinite Ca[(UO2)(AsO4)]2.8H2O. Journal of Raman Spectroscopy, 40(12), pp. 1786-1790.

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Abstract

Raman spectra of metauranospinite Ca[(UO2)(AsO4)]2.8H2O complemented with infrared spectra were studied. Observed bands were assigned to the stretching and bending vibrations of (UO2)2+ and (AsO4)3- units and of water molecules. U-O bond lengths in uranyl and O-H…O hydrogen bond lengths were calculated from the Raman and infrared spectra.

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6 citations in Web of Science®

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64 since deposited on 18 Dec 2009
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ID Code: 29363
Item Type: Journal Article
Keywords: metauranospinite, mineral, uranyl, arsenate, molecular water, Raman, infrared, spectroscopy
DOI: 10.1002/jrs.2242
ISSN: 0377-0486
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Colloid and Surface Chemistry (030603)
Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600)
Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606)
Divisions: Past > QUT Faculties & Divisions > Faculty of Science and Technology
Past > Schools > School of Physical & Chemical Sciences
Copyright Owner: Copyright 2009 John Wiley & Sons, Ltd.
Copyright Statement: The definitive version is available at www3.interscience.wiley.com
Deposited On: 18 Dec 2009 12:01
Last Modified: 01 Mar 2012 00:07

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