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Isopropylaminium 2-carboxy-4, 5-dichlorobenzoate

Smith, Graham & Wermuth, Urs D. (2010) Isopropylaminium 2-carboxy-4, 5-dichlorobenzoate. Acta Crystallographica. Section E : Structure Reports Online, 66(1), o133.

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Abstract

In the structure of the 1:1 proton-transfer compound of isopropylamine with 4,5-dichlorophthalic acid, C3H10N+·C8H3Cl2O4-, the three cation H-atom donors associate with three separate carboxyl O-atom anion acceptors, giving conjoint cyclic R44(12), R44(16) hydrogen-bonding cation-anion interactions in a one-dimensional ribbon structure. In the anions, the carboxyl groups lie slightly out of the plane of the benzene ring [maximum deviations = 0.439 (1) for a carboxylic acid O atom and 0.433 (1) Å for a carboxylate O atom]. However, the syn-related proton of the carboxylic acid group forms the common short intramolecular O-HOcarboxyl hydrogen bond.

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4 citations in Web of Science®

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21 since deposited on 22 Feb 2010
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ID Code: 31035
Item Type: Journal Article
Additional URLs:
Keywords: crystal structure, proton-transfer compounds, hydrogen bonding, 4,5-dichlorophthalate
DOI: 10.1107/S1600536809052672
ISSN: 1600-5368
Divisions: Past > Schools > Chemistry
Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright 2010 International Union of Crystallography
Copyright Statement: This open-access article is distributed under the terms of the Creative Commons Attribution Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
Deposited On: 23 Feb 2010 07:53
Last Modified: 01 Mar 2012 00:26

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