Isopropylaminium 2-carboxy-4, 5-dichlorobenzoate
In the structure of the 1:1 proton-transfer compound of isopropylamine with 4,5-dichlorophthalic acid, C3H10N+·C8H3Cl2O4-, the three cation H-atom donors associate with three separate carboxyl O-atom anion acceptors, giving conjoint cyclic R44(12), R44(16) hydrogen-bonding cation-anion interactions in a one-dimensional ribbon structure. In the anions, the carboxyl groups lie slightly out of the plane of the benzene ring [maximum deviations = 0.439 (1) for a carboxylic acid O atom and 0.433 (1) Å for a carboxylate O atom]. However, the syn-related proton of the carboxylic acid group forms the common short intramolecular O-HOcarboxyl hydrogen bond.
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|Item Type:||Journal Article|
|Keywords:||crystal structure, proton-transfer compounds, hydrogen bonding, 4,5-dichlorophthalate|
|Divisions:||Past > Schools > Chemistry
Past > QUT Faculties & Divisions > Faculty of Science and Technology
|Copyright Owner:||Copyright 2010 International Union of Crystallography|
|Copyright Statement:||This open-access article is distributed under the terms of the Creative Commons Attribution Licence
http://creativecommons.org/licenses/by/2.0/uk/legalcode, which permits unrestricted use, distribution, and
reproduction in any medium, provided the original authors and source are cited.
|Deposited On:||22 Feb 2010 21:53|
|Last Modified:||29 Feb 2012 14:26|
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