Isopropylaminium 2-carboxy-4, 5-dichlorobenzoate
Smith, Graham & Wermuth, Urs D. (2010) Isopropylaminium 2-carboxy-4, 5-dichlorobenzoate. Acta Crystallographica. Section E : Structure Reports Online, 66(1), o133.
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Abstract
In the structure of the 1:1 proton-transfer compound of isopropylamine with 4,5-dichlorophthalic acid, C3H10N+·C8H3Cl2O4-, the three cation H-atom donors associate with three separate carboxyl O-atom anion acceptors, giving conjoint cyclic R44(12), R44(16) hydrogen-bonding cation-anion interactions in a one-dimensional ribbon structure. In the anions, the carboxyl groups lie slightly out of the plane of the benzene ring [maximum deviations = 0.439 (1) for a carboxylic acid O atom and 0.433 (1) Å for a carboxylate O atom]. However, the syn-related proton of the carboxylic acid group forms the common short intramolecular O-HOcarboxyl hydrogen bond.
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| ID Code: | 31035 |
|---|---|
| Item Type: | Journal Article |
| Additional URLs: | |
| Keywords: | crystal structure, proton-transfer compounds, hydrogen bonding, 4,5-dichlorophthalate |
| DOI: | 10.1107/S1600536809052672 |
| ISSN: | 1600-5368 |
| Divisions: | Past > Schools > Chemistry Past > QUT Faculties & Divisions > Faculty of Science and Technology |
| Copyright Owner: | Copyright 2010 International Union of Crystallography |
| Copyright Statement: | This open-access article is distributed under the terms of the Creative Commons Attribution Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| Deposited On: | 23 Feb 2010 07:53 |
| Last Modified: | 01 Mar 2012 00:26 |
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