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A novel profluorescent dinitroxide for imaging polypropylene degradation

Fairfull-Smith, Kathryn E., Blinco, James P., Keddie, Daniel J., George, Graeme A., & Bottle, Steven E. (2008) A novel profluorescent dinitroxide for imaging polypropylene degradation. Macromolecules, 41(5), pp. 1577-1580.

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Abstract

Free-radical processes underpin the thermo-oxidative degradation of polyolefins. Thus, to extend the lifetime of these polymers, stabilizers are generally added during processing to scavenge the free radicals formed as the polymer degrades. Nitroxide radical precursors, such as hindered amine stabilizers (HAS),1,2 are common polypropylene additives as the nitroxide moiety is a potent scavenger of polymer alkyl radicals (R¥). Oxidation of HAS by radicals formed during polypropylene degradation yields nitroxide radicals (RRNO¥), which rapidly trap the polymer degradation species to produce alkoxyamines, thus retarding oxidative polymer degradation. This increase in polymer stability is demonstrated by a lengthening of the “induction period” of the polymer (the time prior to a sharp rise in the oxidation of the polymer). Instrumental techniques such as chemiluminescence or infrared spectroscopy are somewhat limited in detecting changes in the polymer during the initial stages of degradation. Therefore, other methods for observing polymer degradation have been sought as the useful life of a polymer does not extend far beyond its “induction period”

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25 citations in Scopus
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23 citations in Web of Science®

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ID Code: 31135
Item Type: Journal Article
Additional Information: This article is freely available from the American Chemical Society website 12 months after the publication date. See links to publisher website in this record.
Keywords: Profluorescence, Nitroxide, Polypropylene, Degradation, Imaging
DOI: 10.1021/ma701944p
ISSN: 0024-9297
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > MACROMOLECULAR AND MATERIALS CHEMISTRY (030300) > Chemical Characterisation of Materials (030301)
Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > MACROMOLECULAR AND MATERIALS CHEMISTRY (030300) > Optical Properties of Materials (030303)
Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > ANALYTICAL CHEMISTRY (030100)
Divisions: Past > QUT Faculties & Divisions > Faculty of Science and Technology
Deposited On: 04 Mar 2010 15:53
Last Modified: 01 Mar 2012 13:50

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