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Near infrared spectroscopy of benzoic acid adsorbed on montmorillonite

Frost, Ray L., Liu, Longfei, & Cai , Jingong (2010) Near infrared spectroscopy of benzoic acid adsorbed on montmorillonite. Spectroscopy Letters, 43(4), pp. 266-274.

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Abstract

The adsorption of benzoic acid on both sodium and calcium montmorillonites has been studied by near infrared spectroscopy complimented with infrared spectroscopy. Upon adsorption of benzoic acid additional near infrared bands are observed at 8665 cm-1 and assigned to an interaction of benzoic acid with the water of hydration. Upon adsorption of the benzoic acid on Na-Mt, the NIR bands are now observed at 5877, 5951, 6028 and 6128 cm-1 and are assigned to the overtone and combination bands of the CH fundamentals. Additional bands at 4074, 4205, 4654 and 4678 cm-1 are attributed to CH combination bands resulting from the adsorption of the benzoic acid. Benzoic acid is used as a model molecule for adsorption studies. The application of near infrared spectroscopy to the study of adsorption has the potential for the removal of acids from polluted aqueous systems.

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ID Code: 32136
Item Type: Journal Article
Additional URLs:
Keywords: montmorillonites, benzoic acid, near infrared spectroscopy, adsorption, structured water
DOI: 10.1080/00387010903329417
ISSN: 0038-7010
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600)
Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606)
Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Chemical Thermodynamics and Energetics (030602)
Divisions: Past > Schools > Chemistry
Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright 2010 Taylor and Francis
Deposited On: 07 May 2010 07:47
Last Modified: 01 Mar 2012 00:15

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