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Low temperature synthesis of zeolite N from kaolinites and montmorillonites

Mackinnon, Ian D.R., Millar, Graeme J., & Stolz, Wanda (2010) Low temperature synthesis of zeolite N from kaolinites and montmorillonites. Applied Clay Science, 48(4), pp. 622-630.

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Abstract

Zeolite N was produced from a variety of kaolinites and montmorillonites at low temperature (b100 °C) in a constantly stirred reactor using potassic and potassic+sodic mother liquors with chloride or hydroxyl anions. Reactions were complete (N95% product) in less than 20 h depending on initial batch composition and type of clay minerals. Zeolite N with 1.0bSi/Alb2.2 was produced under these conditions using KOH in the presence of KCl, NaCl, KCl+NaCl and KCl+NaOH. Zeolite N was also formed under high potassium molarities in the absence of KCl. Zeolite synthesis was more sensitive to water content and temperature when sodium was used in initial batch compositions. Syntheses of zeolite N by these methods were undertaken at bench, pilot and industrial scales.

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4 citations in Scopus
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3 citations in Web of Science®

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ID Code: 32426
Item Type: Journal Article
Additional URLs:
Keywords: kaolinite, montmorillonite, zeolite N synthesis, cation exchange
DOI: 10.1016/j.clay.2010.03.016
ISSN: 0169-1317
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > MACROMOLECULAR AND MATERIALS CHEMISTRY (030300)
Divisions: Current > QUT Faculties and Divisions > Division of Research and Commercialisation
Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright 2010 Elsevier
Deposited On: 31 May 2010 08:20
Last Modified: 21 Jan 2013 09:14

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