Optical absorption near infrared and EPR studies of mottramite
Frost, Ray L., Reddy, S. Lakshmi , Reddy, K. N. M. , Reddy, G. Siva , & Endo, Tamio (2010) Optical absorption near infrared and EPR studies of mottramite. Molecular Physics, 108(11), pp. 1467-1470.
Mottramite mineral originated from Tsumeb Corporation Mine, Tsumeb, Otavi, Namibia, is used in the present work. The mineral contains of vanadium and copper to the extent of 22.73% and 16.84% by weight respectively as V2O5 and CuO. An EPR study of sample confirms the presence of Cu(II) with g = 2.2. Optical absorption spectrum of mottramite indicates that Cu(II) is present in rhombic environment. NIR results are due to water fundamentals.
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|Item Type:||Journal Article|
|Keywords:||Mottramite mineral, Cu(II), rhombic distortion, EPR, Optical absorption,|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600)|
Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606)
Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Physical Chemistry not elsewhere classified (030699)
|Divisions:||Past > Schools > Chemistry|
Past > QUT Faculties & Divisions > Faculty of Science and Technology
|Copyright Owner:||Copyright 2010 Taylor & Francis|
|Deposited On:||25 Jun 2010 08:00|
|Last Modified:||01 Mar 2012 00:16|
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