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Highly efficient, stoichiometric radical exchange reactions using isoindoline profluorescent nitroxides

Blinco, James P., Fairfull-Smith, Kathryn E., Micallef, Aaron, & Bottle, Steven (2010) Highly efficient, stoichiometric radical exchange reactions using isoindoline profluorescent nitroxides. Polymer Chemistry, 2010(7), pp. 1009-1012.

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Abstract

Exchange reactions between the isoindoline profluorescent nitroxide 1,1,3,3-tetramethyldibenzo[e,g]isoindolin-2-yloxyl (TMDBIO) and a TEMPO capped polystyrene were carried out. High conversions to the desired products were achieved using only stoichiometric ratios of nitroxide relative to polymer. The scope of this study was expanded by exploiting a di-nitroxide 9,10-bis(5-[1,1,3,3-tetramethylisoindolin-2-yloxy])anthracene (BTMIOA) as a connector between two polymer chains forming PS–nitroxide–PS systems.

Impact and interest:

13 citations in Scopus
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14 citations in Web of Science®

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44 since deposited on 11 Nov 2010
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ID Code: 38450
Item Type: Journal Article
Keywords: nitroxides, radical exchange reactions
DOI: 10.1039/c0py00015a
ISSN: 1759-9954
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > MACROMOLECULAR AND MATERIALS CHEMISTRY (030300) > Synthesis of Materials (030306)
Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > MACROMOLECULAR AND MATERIALS CHEMISTRY (030300) > Macromolecular and Materials Chemistry not elsewhere classified (030399)
Divisions: Past > Schools > Chemistry
Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright 2010 The Royal Society of Chemistry
Deposited On: 12 Nov 2010 07:57
Last Modified: 01 Mar 2012 00:30

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