Highly efficient, stoichiometric radical exchange reactions using isoindoline profluorescent nitroxides
Blinco, James P., Fairfull-Smith, Kathryn E., Micallef, Aaron, & Bottle, Steven (2010) Highly efficient, stoichiometric radical exchange reactions using isoindoline profluorescent nitroxides. Polymer Chemistry, 2010(7), pp. 1009-1012.
Exchange reactions between the isoindoline profluorescent nitroxide 1,1,3,3-tetramethyldibenzo[e,g]isoindolin-2-yloxyl (TMDBIO) and a TEMPO capped polystyrene were carried out. High conversions to the desired products were achieved using only stoichiometric ratios of nitroxide relative to polymer. The scope of this study was expanded by exploiting a di-nitroxide 9,10-bis(5-[1,1,3,3-tetramethylisoindolin-2-yloxy])anthracene (BTMIOA) as a connector between two polymer chains forming PS–nitroxide–PS systems.
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|Item Type:||Journal Article|
|Keywords:||nitroxides, radical exchange reactions|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > MACROMOLECULAR AND MATERIALS CHEMISTRY (030300) > Synthesis of Materials (030306)|
Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > MACROMOLECULAR AND MATERIALS CHEMISTRY (030300) > Macromolecular and Materials Chemistry not elsewhere classified (030399)
|Divisions:||Past > Schools > Chemistry|
Past > QUT Faculties & Divisions > Faculty of Science and Technology
|Copyright Owner:||Copyright 2010 The Royal Society of Chemistry|
|Deposited On:||12 Nov 2010 07:57|
|Last Modified:||01 Mar 2012 00:30|
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