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4-Carbamoylpiperidinium acetate monohydrate

Smith, Graham & Wermuth, Urs D. (2010) 4-Carbamoylpiperidinium acetate monohydrate. Acta Crystallographica. Section E : Structure Reports Online, 66(12), o3162.

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Abstract

In the structure of the title compound, C6H13N2O+ C2H3O2- . H2O, the amide H atoms of the cations form centrosymetric cyclic hydrogen-bonding associations incorporating two water molecules [graph set R^2^~4~(8)], which are conjoint with cyclic water-bridged amide-amide associations [R^4^~4~(12)] and larger R4/4(20) associations involving the water molecule and the acetate anions, which bridge through the piperidinium H donors, giving an overall three-dimensional framework structure.

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11 citations in Scopus
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9 citations in Web of Science®

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22 since deposited on 29 Nov 2010
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ID Code: 38909
Item Type: Journal Article
Keywords: crystal structure, hydrogen bonding, proton transfer, isonipecotamide
DOI: 10.1107/S1600536810045538
ISSN: 1600-5368
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606)
Divisions: Past > Schools > Chemistry
Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Open Access - Attribution
Copyright Statement: This open-access article is distributed under the terms of the Creative Commons Attribution Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
Deposited On: 29 Nov 2010 14:51
Last Modified: 01 Mar 2012 00:27

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