4-Carbamoylpiperidinium phenylacetate hemihydrate

Smith, Graham & Wermuth, Urs D. (2010) 4-Carbamoylpiperidinium phenylacetate hemihydrate. Acta Crystallographica. Section E: Structure Reports Online, 66(12), o3260.

Published Version (PDF 567Kb)
Available under License Creative Commons Attribution 3.0 Australia.

View at publisher

Abstract

In the structure of the title compound, C6H13N2O+ C8H7O2- . 0.5H2O, the asymmetric unit comprises two isonipecotamide cations, two phenylacetate anions and a water molecule of solvation. The hydrogen-bonding environments for both sets of ion pairs are essentially identical with the piperidinium and amide 'ends' of each
cation involved in lateral heteromolecular hydrogen-bonded cyclic N---H...O associations [graph set R2/2(11)] which incorporate a single carboxyl O-atom acceptor. These cyclic motifs enclose larger R5/5(21) cyclic systems forming sheet substructures which lie parallel to (101) and are linked across <i>b</i> by the single water molecule via water O---H...O(carboxyl) associations to give a two-dimensional
duplex-sheet structure

Citations:

6 times in Scopus

Search Google Scholar™

5 times in Web of Science

Citation countsare sourced monthly from Scopus and Web of Science citation databases.

These databases contain citations from different subsets of available publications and different time periods and thus the citation count from each is usually different. Some works are not in either database and no count is displayed. Scopus includes citations from articles published in 1996 onwards, and Web of Science generally from 1980 onwards.

Citations counts from the Google Scholar™ indexing service can be viewed at the linked Google Scholar™ search.

Full-text downloads:

7 since deposited on 29 Nov 2010

1 in the past twelve months

Full-text downloadsdisplays the total number of times this work’s files (e.g., a PDF) have been downloaded from QUT ePrints as well as the number of downloads in the previous 365 days. The count includes downloads for all files if a work has more than one.

More statistics...

ID Code:	38910
Item Type:	Journal Article
Keywords:	crystal structure, hydrogen bonding, proton transfer, isonipecotamide
DOI:	10.1107/S1600536810047872
ISSN:	1600-5368
Subjects:	Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606)
Divisions:	Past > Schools > Chemistry Current > Schools > Drama Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner:	Open Access - Attribution
Copyright Statement:	This open-access article is distributed under the terms of the Creative Commons Attribution Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
Deposited On:	29 Nov 2010 14:39
Last Modified:	01 Mar 2012 00:27

Export: EndNote | Dublin Core | BibTeX

Repository Staff Only: item control page