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Organometallic macrocyclic chemistry. 8.(1) : an unusual metallacycle derived from phosphine−alkynyl thioether coupling

Hill, Anthony F. , Niess, Barbara , Schultz, Madeleine, White, Andrew J., & Williams, David J. (2010) Organometallic macrocyclic chemistry. 8.(1) : an unusual metallacycle derived from phosphine−alkynyl thioether coupling. Organometallics, 29(23), pp. 6488-6492.

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Abstract

The α,ω-diyne 4,7,10-trithiatrideca-2,11-diyne reacts with [RuCl2(PPh3)3] and KPF6 to form the phosphonio-substituted metallatricyclic salt [RuCl(PPh3){κ4C,S,S′,S′′-S(C≡CMe)C2H4SC2H4SC(PPh3)CMe}]PF6 arising from the activation of one alkynyl group toward nucleophilic attack by extraneous phosphine.

Impact and interest:

2 citations in Scopus
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2 citations in Web of Science®

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ID Code: 39074
Item Type: Journal Article
Additional Information: This article is freely available from the American Chemical Society website 12 months after the publication date. See links to publisher website in this record.
Keywords: ruthenium, metallacycle, alkyne cleavage
DOI: 10.1021/om100835r
ISSN: 0276-733
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > OTHER CHEMICAL SCIENCES (039900) > Organometallic Chemistry (039904)
Divisions: Past > Schools > Chemistry
Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright 2010 American Chemical Society
Deposited On: 09 Dec 2010 11:04
Last Modified: 01 Mar 2012 00:26

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