Organometallic macrocyclic chemistry. 8.(1) : an unusual metallacycle derived from phosphine−alkynyl thioether coupling
Hill, Anthony F., Niess, Barbara, Schultz, Madeleine, White, Andrew J., & Williams, David J. (2010) Organometallic macrocyclic chemistry. 8.(1) : an unusual metallacycle derived from phosphine−alkynyl thioether coupling. Organometallics, 29(23), pp. 6488-6492.
Abstract
The α,ω-diyne 4,7,10-trithiatrideca-2,11-diyne reacts with [RuCl2(PPh3)3] and KPF6 to form the phosphonio-substituted metallatricyclic salt [RuCl(PPh3){κ4C,S,S′,S′′-S(C≡CMe)C2H4SC2H4SC(PPh3)CMe}]PF6 arising from the activation of one alkynyl group toward nucleophilic attack by extraneous phosphine.
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| ID Code: | 39074 |
|---|---|
| Item Type: | Journal Article |
| Additional Information: | This article is freely available from the American Chemical Society website 12 months after the publication date. See links to publisher website in this record. |
| Keywords: | ruthenium, metallacycle, alkyne cleavage |
| DOI: | 10.1021/om100835r |
| ISSN: | 0276-733 |
| Subjects: | Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > OTHER CHEMICAL SCIENCES (039900) > Organometallic Chemistry (039904) |
| Divisions: | Past > Schools > Chemistry Past > QUT Faculties & Divisions > Faculty of Science and Technology |
| Copyright Owner: | Copyright 2010 American Chemical Society |
| Deposited On: | 09 Dec 2010 11:04 |
| Last Modified: | 01 Mar 2012 00:26 |
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