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4-Carbamoylpiperidinium 2-carboxybenzoate-benzene-1,2-dicarboxylic acid (1/1)

Smith, Graham & Wermuth, Urs D. (2011) 4-Carbamoylpiperidinium 2-carboxybenzoate-benzene-1,2-dicarboxylic acid (1/1). Acta Crystallographica. Section E: Structure Reports Online, 67(3), o556-o556.

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Abstract

In the structure of the title salt adduct, C6H13N2O+ C8H5O4- . C8H6O4, the asymmetric unit comprises one isonipecotamide cation, a hydrogen phthalate anion and a phthalic acid adduct molecule and form a two-dimensional hydrogen-bonded network through head-to-tail cation-anion-adduct molecule interactions which include a cyclic heteromolecular amide--carboxylate motif [graph set R2/2(8)], conjoint cyclic R2/2(6) and R3/3(10) piperidinium N-H...O(carboxyl) associations, as well as strong carboxylic acid O-H...O(carboxyl) hydrogen bonds.

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3 citations in Scopus
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2 citations in Web of Science®

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11 since deposited on 18 Feb 2011
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ID Code: 40189
Item Type: Journal Article
Keywords: crystal structure, hydrogen bonding, proton transfer, adduct, isonipecotamide
DOI: 10.1107/S1600536811003825
ISSN: 1600-5368
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606)
Divisions: Past > Schools > Chemistry
Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright 2010 please consult authors
Deposited On: 18 Feb 2011 02:00
Last Modified: 18 Feb 2011 02:01

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