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Raman spectroscopy of hydrogen arsenate group (AsO3OH)2− in solid-state compounds: cobalt-containing zinc arsenate mineral, koritnigite (Zn,Co)(AsO3OH)·H2O

Frost, Ray L., Sejkora, Jiri, Cejka, Jiri, Plasil, Jakub, Bahfenne, Silmarilly, & Keeffe, Elloise C. (2011) Raman spectroscopy of hydrogen arsenate group (AsO3OH)2− in solid-state compounds: cobalt-containing zinc arsenate mineral, koritnigite (Zn,Co)(AsO3OH)·H2O. Journal of Raman Spectroscopy, 42(3), pp. 534-539.

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Abstract

Raman spectra of two well-defined types of koritnigite crystals from the Jáchymov ore district, Czech Republic, were recorded and interpreted. No substantial differences were observed between both crystal types. Observed Raman bands were attributed to the (AsO3OH)2- stretching and bending vibrations, stretching and bending vibrations of water molecules and hydroxyl ions. Non-interpreted Raman spectra of koritnigite from the RRUFF database, and published infrared spectra of cobaltkoritnigite were used for comparison. The O-H...O hydrogen bond lengths in the crystal structure of koritnigite were inferred from the Raman spectra and compared with those derived from the X-ray single crystal refinement. The presence of (AsO3OH)2- units in the crystal structure of koritnigite was proved from the Raman spectra which supports the conclusions of the X-ray structure analysis.

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8 citations in Web of Science®

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ID Code: 40858
Item Type: Journal Article
Keywords: koritnigite, mineral, hydrogen-arsenate, Raman spectroscopy, molecular water, hydrogen bonds
DOI: 10.1002/jrs.2690
ISSN: 0377-0486
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606)
Divisions: Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright © 2010 John Wiley & Sons, Ltd.
Deposited On: 22 Mar 2011 08:49
Last Modified: 01 Apr 2012 00:10

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