Smith, Graham, Wermuth, Urs D., & White, Jonathon M. (2011) 2-(4-Aminophenyl)-1-phenyldiazenium 2,4,6-trinitrophenolate. Acta Crystallographica. Section E : Structure Reports Online, 67(4), o878-o878.
In the structure of the title salt, C12H12N3+ C6H2N3O7-, the diazenyl group of the 4-(phenyldiazenyl)aniline molecule is protonated and forms a hydrogen bond with the phenolate O acceptor of the picrate anion. Structure extension occurs through two symmetrical inter-ion three-centre amine N---H...O,O'(nitro) hydrogen-bonding associations [graph set R2/1(4)] giving a convoluted two-dimensional network structure.
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|Item Type:||Journal Article|
|Keywords:||crystal structure, hydrogen bonding, proton transfer, picrates, aniline yellow|
|Divisions:||Past > Schools > Chemistry
Past > QUT Faculties & Divisions > Faculty of Science and Technology
|Copyright Owner:||Copyright 2011 IUCr & The Authors|
|Copyright Statement:||This open-access article is distributed under the terms of the Creative Commons Attribution Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.|
|Deposited On:||27 Mar 2011 23:20|
|Last Modified:||10 Aug 2011 18:17|
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