Infrared spectroscopic study of halloysite-potassium acetate intercalation complex
Frost, Ray L., Cheng, Hongfei, Yang, Jing, Liu , Qinfu , & Zhang , Jinshan (2011) Infrared spectroscopic study of halloysite-potassium acetate intercalation complex. Journal of Molecular Structure, 990(1-3), pp. 21-25.
Mid-infrared (MIR) and near-infrared (NIR) spectroscopy have been used to study the molecular structure of halloysite and potassium acetate intercalated halloysite and to determine the structural changes of halloysite through intercalation. The MIR spectra show all fundamental vibrations including the hydroxyl units, basic aluminosilicate framework and water molecules in the structure of halloysite and its intercalation complex. Comparison between halloysite and halloysite-potassium acetate intercalation complex shows almost all bands observed for halloysite are also observed for halloysite-potassium acetate intercalation complex apart from bands observed in the 1700-1300 cm-1 region, but with differences in band intensity. However, NIR, based on MIR spectra, provide sufficient evidence to analyze the structural changes of halloysite through intercalation. There are obvious differences between halloysite and halloysite-potassium acetate intercalation complex in the all spectral ranges. Therefore, the reproducibility of measurement and richness of qualitative information should be simultaneously considered for proper selection of a spectroscopic method for molecular structural analysis.
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|Item Type:||Journal Article|
|Keywords:||Halloysite; Potassium acetate; Intercalation complex; Near-infrared spectroscopy; Mid-infrared spectroscopy|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606)|
|Divisions:||Past > Schools > Chemistry|
Past > QUT Faculties & Divisions > Faculty of Science and Technology
|Copyright Owner:||Copyright 2011 Elsevier|
|Deposited On:||30 Mar 2011 14:13|
|Last Modified:||30 Apr 2013 12:32|
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