QUT ePrints

The hydrogen-bonded coordination polymer tetracesium bis(5-nitroisophthalate) heptahydrate

Smith, Graham & Wermuth, Urs D. (2011) The hydrogen-bonded coordination polymer tetracesium bis(5-nitroisophthalate) heptahydrate. Journal of Chemical Crystallography, 41(5), pp. 688-692.

View at publisher

Abstract

The coordination polymer complex tetracesium bis(5-nitroisophthalate) heptahydrate [Cs4(C8H3NO6)2 (H2O)7]n has been synthesized and characterized using single-crystal X-ray diffraction. Crystals are monoclinic, space group P21/c, with Z = 4 in a cell with dimensions a = 12.3213(3), b =6.7557(2) c = 36.2020(9) Å, β = 90.548(2)o. The complex is based on a repeating unit comprising four independent and different Cs coordination centres, two 6-coordinate, and two 8-coordinate [Cs-O, range 2.959(5)-3.386(5)Å], and seven water molecules, two of which are monodentate and the other five bridging, while all other oxygen atoms in the structure, including those of the nitro groups form inter-Cs bridges. Extensive water O-H…O hydrogen-bonding interactions give a three-dimensional framework. This structure represents the first of an alkali metal compound of 5-nitroisophthalic acid that has been reported.

Impact and interest:

4 citations in Scopus
Search Google Scholar™
2 citations in Web of Science®

Citation countsare sourced monthly from Scopus and Web of Science® citation databases.

These databases contain citations from different subsets of available publications and different time periods and thus the citation count from each is usually different. Some works are not in either database and no count is displayed. Scopus includes citations from articles published in 1996 onwards, and Web of Science® generally from 1980 onwards.

Citations counts from the Google Scholar™ indexing service can be viewed at the linked Google Scholar™ search.

Full-text downloads:

100 since deposited on 03 Apr 2011
13 in the past twelve months

Full-text downloadsdisplays the total number of times this work’s files (e.g., a PDF) have been downloaded from QUT ePrints as well as the number of downloads in the previous 365 days. The count includes downloads for all files if a work has more than one.

ID Code: 41081
Item Type: Journal Article
Keywords: crystal structure, cesium, coordination polymer, hydrogen bonding
DOI: 10.1007/s10870-010-9953-x
ISSN: 1074-1542
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600)
Divisions: Past > Schools > Chemistry
Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright 2011 Springer
Copyright Statement: The original publication is available at SpringerLink http://www.springerlink.com
Deposited On: 04 Apr 2011 07:41
Last Modified: 05 Apr 2011 08:04

Export: EndNote | Dublin Core | BibTeX

Repository Staff Only: item control page