Bis(guanidinium) 4,5-dichlorophthalate monohydrate

Smith, Graham & Wermuth, Urs D. (2011) Bis(guanidinium) 4,5-dichlorophthalate monohydrate. Acta Crystallographica Section E : Structure Reports Online, 67(7), o1645-o1645.

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In the structure of the title hydrate salt 2(CH6N3)+ C8H2Cl2O42- . H2O, the planes of the carboxylate groups of the dianion are rotated out of the plane of the benzene ring [dihedral angles 48.42(10) and 55.64(9)deg.]. A duplex-sheet structure is formed through guanidinium-carboxylate N-H...O, guanidinium-water N-H...O, and water-carboxylate O-H..O hydrogen-bonding associations.

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ID Code: 42012
Item Type: Journal Article
Refereed: Yes
Keywords: crystal structure, hydrogen bonding, guanidinium salt, 4,5-dichlorophthalate
DOI: 10.1107/S1600536811021192
ISSN: 1600-5368
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600)
Divisions: Past > Schools > Chemistry
Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright 2011 International Union of Crystallography
Deposited On: 16 Jun 2011 22:25
Last Modified: 16 Jun 2011 22:25

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