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The application of Raman spectroscopy to the study of the uranyl mineral coconinoite Fe2Al2(UO2)2(PO4)4(SO4)(OH)2•20H2O

Frost, Ray L., Palmer, Sara J., & Cejka, Jiri (2011) The application of Raman spectroscopy to the study of the uranyl mineral coconinoite Fe2Al2(UO2)2(PO4)4(SO4)(OH)2•20H2O. Spectroscopy Letters, 44(6), pp. 381-387.

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Abstract

Raman spectra of the uranyl containing mineral coconinoite, Fe2Al2(UO2)2(PO4)4(SO4)(OH)2•20H2O, are presented and compared with the mineral’s infrared spectra. Bands connected with (UO2)2+, (PO4)3- , (SO4)2-, (OH)- and H2O stretching and bending vibrations, are assigned. Approximate U-O bond lengths in uranyl, (UO2)2+, and O-H...O hydrogen bond lengths are calculated from the wavenumbers of the U-O stretching vibrations and (OH)- and H2O stretching vibrations, respectively, and compared with published data for similar natural and synthetic compounds.

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ID Code: 42486
Item Type: Journal Article
Keywords: coconinoite, mineral, uranyl, phosphate, sulphate, hydroxyl, water molecules, Raman spectroscopy, infrared spectroscopy
DOI: 10.1080/00387010.2010.551445
ISSN: 0038-7010
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606)
Divisions: Past > Schools > Chemistry
Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright 2011 Taylor Francis
Copyright Statement: This is an electronic version of an article published in [Spectroscopy Letters, 44(6), pp.381-387]. [Spectroscopy Letters] is available online at informaworldTM
Deposited On: 08 Jul 2011 09:49
Last Modified: 09 May 2014 16:26

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