Smith, Graham & Wermuth, Urs D. (2011) Poly[di-mu-aqua-bis(mu-2-amino-4-nitrobenzoato)dicaesium]. Acta Crystallographica Section E, 67, m1047-m1048.

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In the structure of title compound [Cs2(C7H5N2O4)2(H2O)2]n the asymmetric unit comprises two independent and different Cs centres, one nine-coordinate, the other seven coordinate, with both having irregular stereochemistry. The CsO9 coordination comprises oxygen donors from three bridging water molecules, one of which is doubly bridging, three from carboxylate groups, and three from nitro groups, of which two are bidentate chelate bridging. The CsO6N coordination comprises the two bridging water molecules, one amine N donor, one carboxyl O donor and four O donors from nitro groups (two from the chelate bridges). The extension of the dimeric unit gives a two-dimensional polymeric structure which is stabilized by both intra- and intermolecular amine N-H...O and water O-H...O hydrogen bonds to carboxyl O acceptors, as well as inter-ring pi-pi interactions [minimum ring centroid separation, 3.4172(15)A].

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ID Code: 43311
Item Type: Journal Article
Refereed: Yes
Keywords: crystal structure, caesium, coordination complex, 4-nitroanthranilic acid
DOI: 10.1107/S1600536811026614
ISSN: 1600-5368
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606)
Divisions: Past > Schools > Chemistry
Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright 2011 Graham Smith and Urs D. Wermuth
Deposited On: 14 Jul 2011 22:52
Last Modified: 16 Jul 2011 21:27

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