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[P,P-Di-tert-butyl-N-trimethylsilyl- P-(trimethylsilylamino)phosphineimidato-N,N]bis(pyridine-N)- lithium(I)

Schultz, Madeleine, Straub, Bernd, & Hofmann, Peter (2002) [P,P-Di-tert-butyl-N-trimethylsilyl- P-(trimethylsilylamino)phosphineimidato-N,N]bis(pyridine-N)- lithium(I). Acta Crystallographica, Section C, C58, m256-m257.

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Abstract

In the title compound, [Li(C14H36N2PSi2)(C5H5N)2], the bulky chelating monoanionic P,P-di-tert-butyl-N-trimethylsilyl-P-(trimethylsilylamino)phosphine imidate ligand and two pyridine ligands bind to Li in a pseudo-tetrahedral arrangement with twofold symmetry. The Li-N [phosphine]distance is 2.048 (5) Å, while the LiP distance is 2.520 (6) Å

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6 citations in Scopus
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5 citations in Web of Science®

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ID Code: 44216
Item Type: Journal Article
Keywords: imidate ligand, lithium complex, crystal structure
DOI: 10.1107/S0108270102002706
ISSN: 0108-2701
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > INORGANIC CHEMISTRY (030200) > Main Group Metal Chemistry (030204)
Divisions: Past > QUT Faculties & Divisions > Faculty of Science and Technology
Deposited On: 25 Aug 2011 07:51
Last Modified: 25 Aug 2011 07:51

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