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Carbon monoxide and isocyanide complexes of trivalent uranium metallocenes

del Mar Conejo, Maria , Parry, Julian , Carmona, Ernesto , Schultz, Madeleine, Brennann, John , Beshouri, Sharon , Andersen, Richard A. , Rogers, Robin , Coles, Simon , & Hursthouse, Michael (1999) Carbon monoxide and isocyanide complexes of trivalent uranium metallocenes. Chemistry : A European Journal, 5(10), pp. 3000-3009.

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Abstract

The [Cp′3U] metallocenes contain substituted cyclopentadienyl ligands and UIII with f3 electron configuration. They are good π donors and bind π-accepting ligands (L) such as carbon monoxide and isocyanides to form the corresponding adducts [Cp′3U(L)] (see scheme). The π-donating capability of the [Cp′3U] fragments appears to be readily modulated by the substituents on the cyclopentadienyl ligand.

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ID Code: 45449
Item Type: Journal Article
Keywords: f-block organometallic compounds, carbonyl complexes of uranium, X-ray crystallography, infrared spectroscopy
DOI: 10.1002/(SICI)1521-3765(19991001)5:10<3000::AID-CHEM3000>3.0.CO;2-Q
ISSN: 1521-3765
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > OTHER CHEMICAL SCIENCES (039900) > Organometallic Chemistry (039904)
Divisions: Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright 1999 John Wiley and Sons
Deposited On: 26 Aug 2011 08:04
Last Modified: 26 Aug 2011 08:04

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