Diels-Alder reactions as an efficient route to high purity cyclic polymers
Glassner, Mathias, Blinco, James P., & Barner-Kowollik, Christopher (2011) Diels-Alder reactions as an efficient route to high purity cyclic polymers. Macromolecular Rapid Communications, 32(9-10), pp. 724-728.
Abstract
A simple and efficient route for the synthesis of cyclic polymer systems is presented. Linear furan protected α-maleimide-ω-cyclopentadienyl functionalized precursors (poly(methyl methacrylate) and poly(tert-butyl acrylate)) were synthesized via atom transfer radical polymerization (ATRP) and subsequent substitution of the bromine end-group with cyclopentadiene. Upon heating at high dilution, deprotection of the dieneophile occurs followed by an intramolecular Diels–Alder reaction yielding a high purity cyclic product.
Citations:
Citation countsare sourced monthly from Scopus and Web of Science citation databases.
These databases contain citations from different subsets of available publications and different time periods and thus the citation count from each is usually different. Some works are not in either database and no count is displayed. Scopus includes citations from articles published in 1996 onwards, and Web of Science generally from 1980 onwards.
Citations counts from the Google Scholar™ indexing service can be viewed at the linked Google Scholar™ search.
| ID Code: | 45918 |
|---|---|
| Item Type: | Journal Article |
| Keywords: | atom transfer radical polymerization;cyclic polymers;Diels–Alder reactions |
| DOI: | 10.1002/marc.201100094 |
| ISSN: | 1022-1336 |
| Subjects: | Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > MACROMOLECULAR AND MATERIALS CHEMISTRY (030300) Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > MACROMOLECULAR AND MATERIALS CHEMISTRY (030300) > Synthesis of Materials (030306) |
| Divisions: | Past > Schools > Chemistry Past > QUT Faculties & Divisions > Faculty of Science and Technology |
| Deposited On: | 13 Sep 2011 08:29 |
| Last Modified: | 13 Sep 2011 08:29 |
Export: EndNote | Dublin Core | BibTeX
Repository Staff Only: item control page