Formation of nanoporous materials via mild retro-Diels–Alder chemistry
Glassner, Mathias, Blinco, James P., & Barner-Kowollik, Christopher (2011) Formation of nanoporous materials via mild retro-Diels–Alder chemistry. Polymer Chemistry, 2(1), pp. 83-87.
Poly(styrene)-block-poly(ethylene oxide) copolymers synthesized via the combination of reversible addition fragmentation chain transfer (RAFT) polymerization and hetero Diels–Alder (HDA) cycloaddition can be cleaved in the solid state by a retro-HDA reaction occurring at 90 °C. Nanoporous films can be prepared from these polymers using a simple heating and washing procedure.
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|Item Type:||Journal Article|
|Keywords:||RAFT, hetero Diels–Alder, retro-HDA reaction|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > MACROMOLECULAR AND MATERIALS CHEMISTRY (030300)|
|Divisions:||Past > Schools > Chemistry
Past > QUT Faculties & Divisions > Faculty of Science and Technology
|Deposited On:||12 Sep 2011 23:06|
|Last Modified:||27 Jun 2014 01:57|
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