Formation of nanoporous materials via mild retro-Diels–Alder chemistry

Glassner, Mathias, Blinco, James P., & Barner-Kowollik, Christopher (2011) Formation of nanoporous materials via mild retro-Diels–Alder chemistry. Polymer Chemistry, 2(1), pp. 83-87.

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Poly(styrene)-block-poly(ethylene oxide) copolymers synthesized via the combination of reversible addition fragmentation chain transfer (RAFT) polymerization and hetero Diels–Alder (HDA) cycloaddition can be cleaved in the solid state by a retro-HDA reaction occurring at 90 °C. Nanoporous films can be prepared from these polymers using a simple heating and washing procedure.

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28 citations in Scopus
27 citations in Web of Science®
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ID Code: 45926
Item Type: Journal Article
Refereed: Yes
Keywords: RAFT, hetero Diels–Alder, retro-HDA reaction
DOI: 10.1039/c0py00267d
ISSN: 1759-9954
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > MACROMOLECULAR AND MATERIALS CHEMISTRY (030300)
Divisions: Past > QUT Faculties & Divisions > Faculty of Science and Technology
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 12 Sep 2011 23:06
Last Modified: 14 Jul 2017 09:01

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