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Formation of nanoporous materials via mild retro-Diels–Alder chemistry

Glassner, Mathias, Blinco, James P., & Barner-Kowollik, Christopher (2011) Formation of nanoporous materials via mild retro-Diels–Alder chemistry. Polymer Chemistry, 2(1), pp. 83-87.

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Abstract

Poly(styrene)-block-poly(ethylene oxide) copolymers synthesized via the combination of reversible addition fragmentation chain transfer (RAFT) polymerization and hetero Diels–Alder (HDA) cycloaddition can be cleaved in the solid state by a retro-HDA reaction occurring at 90 °C. Nanoporous films can be prepared from these polymers using a simple heating and washing procedure.

Impact and interest:

21 citations in Scopus
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20 citations in Web of Science®

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ID Code: 45926
Item Type: Journal Article
Keywords: RAFT, hetero Diels–Alder, retro-HDA reaction
DOI: 10.1039/c0py00267d
ISSN: 1759-9954
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > MACROMOLECULAR AND MATERIALS CHEMISTRY (030300)
Divisions: Past > Schools > Chemistry
Past > QUT Faculties & Divisions > Faculty of Science and Technology
Deposited On: 13 Sep 2011 09:06
Last Modified: 27 Jun 2014 11:57

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