Smith, Graham, Wermuth, Urs D., & Williams, Michael L. (2011) catena-Poly[[diaqualithium]-mu-[rac-cis-(2-carboxycyclohexane-1-carboxylato-kO1:O2]]. Acta Crystallographica Section E : Structure Reports Online, 67(12), m1658-m1658.
In the structure of the title compound, [C8H11LiO4(H2O)2]n
the distorted tetrahadral LiO4 coordination sphere comprises two water molecules and two carboxyl O-donors from separate bridging cis-2-carboxycyclohexane-1-carboxylate monoanions [Li-O range, 1.887(4)-1.946(3)A], giving chain substructures which extend along (010).
Water-water and water-carboxyl O-H...O hydrogen bonds stabilize these chain structures and provide inter-chain links, resulting in a two-dimensional layered structure extending across (011).
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|Item Type:||Journal Article|
|Additional Information:||Published online November 2011|
|Keywords:||crystal structure, hydrogen-bonding, metal complex, lithium|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600)|
|Divisions:||Past > Schools > Chemistry|
Past > QUT Faculties & Divisions > Faculty of Science and Technology
|Copyright Owner:||Copyright 2011 please consult author|
|Deposited On:||11 Nov 2011 08:55|
|Last Modified:||11 Nov 2011 08:55|
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