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catena-Poly[[diaqualithium]-mu-[rac-cis-(2-carboxycyclohexane-1-carboxylato-kO1:O2]]

Smith, Graham, Wermuth, Urs D., & Williams, Michael L. (2011) catena-Poly[[diaqualithium]-mu-[rac-cis-(2-carboxycyclohexane-1-carboxylato-kO1:O2]]. Acta Crystallographica Section E : Structure Reports Online, 67(12), m1658-m1658.

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Abstract

In the structure of the title compound, [C8H11LiO4(H2O)2]n the distorted tetrahadral LiO4 coordination sphere comprises two water molecules and two carboxyl O-donors from separate bridging cis-2-carboxycyclohexane-1-carboxylate monoanions [Li-O range, 1.887(4)-1.946(3)A], giving chain substructures which extend along (010). Water-water and water-carboxyl O-H...O hydrogen bonds stabilize these chain structures and provide inter-chain links, resulting in a two-dimensional layered structure extending across (011).

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ID Code: 46959
Item Type: Journal Article
Additional Information: Published online November 2011
Keywords: crystal structure, hydrogen-bonding, metal complex, lithium
DOI: 10.1107/S1600536811045077
ISSN: 1600-5368
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600)
Divisions: Past > Schools > Chemistry
Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright 2011 please consult author
Deposited On: 11 Nov 2011 08:55
Last Modified: 11 Nov 2011 08:55

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