Simultaneous voltammetric determination of three herbicides in food and water samples with the aid of chemometrics
Ni, Yongnian, Wang, Lin, & Kokot, Serge (2009) Simultaneous voltammetric determination of three herbicides in food and water samples with the aid of chemometrics. Chemical Research in Chinese Universities, 25(2), pp. 151-154.
Differential pulse stripping voltammetry method(DPSV) was applied to the determination of three herbicides, ametryn, cyanatryn, and dimethametryn. It was found that their voltammograms overlapped strongly, and it is difficult to determine these compounds individually from their mixtures. With the aid of chemometrics, classical least squares(CLS), principal component regression(PCR) and partial least squares(PLS), voltammogram resolution and quantitative analysis of the synthetic mixtures of the three compounds were successfully performed. The proposed method was also applied to the analysis of some real samples with satisfactory results.
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|Item Type:||Journal Article|
|Keywords:||Herbicidal analysis, Chemometrics, Differential pulse stripping voltammetry|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > ANALYTICAL CHEMISTRY (030100) > Quality Assurance Chemometrics Traceability and Metrological Chemistry (030106)
Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > MEDICINAL AND BIOMOLECULAR CHEMISTRY (030400) > Medicinal and Biomolecular Chemistry not elsewhere classified (030499)
Australian and New Zealand Standard Research Classification > ENGINEERING (090000) > FOOD SCIENCES (090800) > Food Chemistry and Molecular Gastronomy (excl. Wine) (090801)
|Divisions:||Past > QUT Faculties & Divisions > Faculty of Science and Technology|
|Copyright Owner:||Copyright 2009 Jilin University|
|Deposited On:||12 Dec 2011 22:13|
|Last Modified:||29 Feb 2012 14:07|
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