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Simultaneous voltammetric determination of three herbicides in food and water samples with the aid of chemometrics

Ni, Yongnian , Wang, Lin , & Kokot, Serge (2009) Simultaneous voltammetric determination of three herbicides in food and water samples with the aid of chemometrics. Chemical Research in Chinese Universities, 25(2), pp. 151-154.

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Abstract

Differential pulse stripping voltammetry method(DPSV) was applied to the determination of three herbicides, ametryn, cyanatryn, and dimethametryn. It was found that their voltammograms overlapped strongly, and it is difficult to determine these compounds individually from their mixtures. With the aid of chemometrics, classical least squares(CLS), principal component regression(PCR) and partial least squares(PLS), voltammogram resolution and quantitative analysis of the synthetic mixtures of the three compounds were successfully performed. The proposed method was also applied to the analysis of some real samples with satisfactory results.

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ID Code: 47615
Item Type: Journal Article
Keywords: Herbicidal analysis, Chemometrics, Differential pulse stripping voltammetry
ISSN: 1005-9040
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > ANALYTICAL CHEMISTRY (030100) > Quality Assurance Chemometrics Traceability and Metrological Chemistry (030106)
Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > MEDICINAL AND BIOMOLECULAR CHEMISTRY (030400) > Medicinal and Biomolecular Chemistry not elsewhere classified (030499)
Australian and New Zealand Standard Research Classification > ENGINEERING (090000) > FOOD SCIENCES (090800) > Food Chemistry and Molecular Gastronomy (excl. Wine) (090801)
Divisions: Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright 2009 Jilin University
Deposited On: 13 Dec 2011 08:13
Last Modified: 01 Mar 2012 00:07

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