Vibrational spectroscopic study of the copper silicate mineral kinoite Ca2Cu2Si3O10(OH)4
Frost, Ray L. & Xi, Yunfei (2012) Vibrational spectroscopic study of the copper silicate mineral kinoite Ca2Cu2Si3O10(OH)4. Spectrochimica Acta Part A : Molecular and Biomolecular Spectroscopy, 89, pp. 88-92.
Kinoite Ca2Cu2Si3O10(OH)4 is a mineral named after a Jesuit missionary. Raman and infrared spectroscopy have been used to characterise the structure of the mineral. The Raman spectrum is characterised by an intense sharp band at 847 cm-1 assigned to the ν1 (A1g) symmetric stretching vibration. Intense sharp bands at 951, 994 and 1000 cm-1 are assigned to the ν3 (Eu, A2u, B1g) SiO4 antisymmetric stretching vibrations. Multiple ν2 SiO4 vibrational modes indicate strong distortion of the SiO4 tetrahedra. Multiple CaO and CuO stretching bands are observed. Raman spectroscopy confirmed by infrared spectroscopy clearly shows that hydroxyl units are involved in the kinoite structure. Based upon the infrared spectra, it is proposed that water is also involved in the kinoite structure. Based upon vibrational spectroscopy, the formula of kinoite is defined as Ca2Cu2Si3O10(OH)4•xH2O.
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|Item Type:||Journal Article|
|Keywords:||kinoite, papagoite, whelanite, stringhamite, cupric ions, healing mineral, vibrational spectroscopy|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606)|
|Divisions:||Past > Schools > Chemistry
Past > QUT Faculties & Divisions > Faculty of Science and Technology
|Copyright Owner:||Copyright 2012 Elsevier|
|Copyright Statement:||This is the author’s version of a work that was accepted for publication in <Spectrochimica Acta Part A : Molecular and Biomolecular Spectroscopy>. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Spectrochimica Acta Part A : Molecular and Biomolecular Spectroscopy, [VOL 89, (2012)] DOI: 10.1016/j.saa.2011.12.051|
|Deposited On:||17 Jan 2012 21:26|
|Last Modified:||19 Jan 2012 05:28|
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