Vibrational spectroscopy and solubility study of the mineral stringhamite CaCuSiO4•H2O
Frost, Ray L. & Xi, Yunfei (2012) Vibrational spectroscopy and solubility study of the mineral stringhamite CaCuSiO4•H2O. Spectrochimica Acta Part A : Molecular and Biomolecular Spectroscopy, 91, pp. 324-328.
Stringhamite CaCuSiO4•H2O is a hydrated calcium copper silicate and is commonly known as a significant ‘healing’ mineral and is potentially a semi-precious jewel. Stringhamite is a neosilicate with Cu2+ in square planar coordination. Vibrational spectroscopy has been used to characterise the molecular structure of stringhamite.
The intense sharp Raman band at 956 cm-1 is assigned to the ν1 (A1g) symmetric stretching vibration. Raman bands at 980, 997, 1061 cm-1 are assigned to the ν3 (A2u, B1g) antisymmetric stretching vibrations. Splitting of the ν3 vibrational mode supports the concept that the stringhamite SiO4 tetrahedron is strongly distorted. The intense bands at 505 and 519 cm-1 and at 570 cm-1 are assigned to the ν2 and ν4 vibrational modes.
The question arises as to whether the mineral stringhamite can actually function as a healing mineral. An estimation of the solubility product at pH < 5 shows that the cupric ion can be released. The copper ion is a very powerful antibiological agent and thus the mineral stringhamite may well function as a healing mineral.
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|Item Type:||Journal Article|
|Keywords:||stringhamite, cupric ions, healing mineral, vibrational spectroscopy, chrysocolla|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606)|
|Divisions:||Current > Schools > School of Chemistry, Physics & Mechanical Engineering|
Current > QUT Faculties and Divisions > Science & Engineering Faculty
|Copyright Owner:||Copyright 2012 Elsevier B.V.|
|Copyright Statement:||NOTICE: this is the author’s version of a work that was accepted for publication in Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy, [VOL 91 (2012)] DOI 10.1016/j.saa.2012.02.007|
|Deposited On:||07 Mar 2012 15:44|
|Last Modified:||19 Apr 2013 18:05|
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