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Phenolics in sugar cane juice : potential degradation by hydrogen peroxide and Fenton’s reagent

Nguyen, Danny M. T. & Doherty, William O. S. (2012) Phenolics in sugar cane juice : potential degradation by hydrogen peroxide and Fenton’s reagent. International Sugar Journal, 114(1361), pp. 309-315.

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    Abstract

    The presence of colour in raw sugar plays a key role in the marketing strategy of the Australian raw sugar industry. Some sugars are relatively difficult to decolourise during refining and develop colour during storage. A new approach that might result in efficient and cost-effective colour removal during the sugar manufacturing process is the use of an advanced oxidation process (AOP), known as Fenton oxidation, that is, catalytic production of hydroxyl radicals from the decomposition of hydrogen peroxide using ferrous iron. As a first step towards developing this technology, this study determined the composition of colour precursors present in the juice of cane harvested by three different methods. The methods were harvesting cane after burning, harvesting the whole crop with half of the trash extracted and harvesting the whole crop with no trash extracted. The study also investigated the degradation at pH 3, 4 and 5 of a phenolic compound, caffeic acid (3,4–dihydroxycinnamic acid), which is present in sugar cane juice, using both hydrogen peroxide and Fenton’s reagent. The results show that juice expressed from whole crop cane has significantly higher colour than juices expressed from burnt cane. However, the concentrations of phenolic acids were lower in the juices expressed from whole crop cane. The main phenolic acids present in these juices were p-coumaric, vanillic, 2,3–dihydroxybenzoic, gallic and 3,4–dihydroxybenzoic acids. The degradation of caffeic acid significantly improved using Fenton’s reagent in comparison to hydrogen peroxide alone. The Fenton oxidation was optimum at pH 5 when up to ~86% of caffeic acid degraded within 5 min.

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    ID Code: 50488
    Item Type: Journal Article
    Additional Information: Pending publication details.
    ISSN: 0020-8841
    Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > ANALYTICAL CHEMISTRY (030100) > Separation Science (030108)
    Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Solution Chemistry (030605)
    Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > OTHER CHEMICAL SCIENCES (039900) > Industrial Chemistry (039903)
    Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
    Current > Research Centres > Centre for Tropical Crops and Biocommodities
    Current > QUT Faculties and Divisions > Science & Engineering Faculty
    Copyright Owner: Copyright 2012 Danny M. T. Nguyen and William O. S. Doherty
    Deposited On: 23 May 2012 09:43
    Last Modified: 13 Dec 2012 07:15

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