QUT ePrints

Dynamic covalent chemistry on surfaces employing highly reactive cyclopentadienyl moieties

Blinco, James P., Trouillet, Vanessa, Bruns, Michael, Gerstel, Peter, Gliemann, Hartmut, & Barner-Kowollik, Christopher (2011) Dynamic covalent chemistry on surfaces employing highly reactive cyclopentadienyl moieties. Advanced Materials, 23(38), pp. 4435-4439.

View at publisher

Abstract

Silicon substrates coated with a bromide-terminated silane are transformed into highly reactive, cyclopentadiene covered analogues. These surfaces undergo rapid cycloaddition reactions with various dienophile-capped polymers. Mild heating of the substrates causes the retro-Diels-Alder reaction to occur, thus reforming the reactive cyclopentadiene surface, generating an efficiently switchable surface.

Impact and interest:

12 citations in Scopus
Search Google Scholar™
11 citations in Web of Science®

Citation countsare sourced monthly from Scopus and Web of Science® citation databases.

These databases contain citations from different subsets of available publications and different time periods and thus the citation count from each is usually different. Some works are not in either database and no count is displayed. Scopus includes citations from articles published in 1996 onwards, and Web of Science® generally from 1980 onwards.

Citations counts from the Google Scholar™ indexing service can be viewed at the linked Google Scholar™ search.

ID Code: 51003
Item Type: Journal Article
Keywords: polymeric materials, stimuli-responsive materials, surface modification, Cycloaddition reaction, Cyclopentadienes, Cyclopentadienyls, Dynamic covalent chemistry, Retro-Diels-Alder reactions, Silicon substrates, Switchable, Bromine compounds, Coated materials, Cycloaddition, Functional polymers, Olefins, Polymers, Surface treatment, Surface reactions, cyclopentane derivative, organosilicon derivative, polymer, article, atomic force microscopy, chemistry, heat, molecular dynamics, surface property, synthesis, temperature, X ray photoelectron spectroscopy, Cyclopentanes, Hot Temperature, Microscopy, Atomic Force, Molecular Dynamics Simulation, Organosilicon Compounds, Photoelectron Spectroscopy, Surface Properties
DOI: 10.1002/adma.201102875
ISSN: 0935-9648
Subjects: Australian and New Zealand Standard Research Classification > ENGINEERING (090000)
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Copyright Owner: Copyright 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Copyright Statement: The definitive version is available at www3.interscience.wiley.com
Deposited On: 21 Jun 2012 14:06
Last Modified: 24 Aug 2012 12:27

Export: EndNote | Dublin Core | BibTeX

Repository Staff Only: item control page