Amphiphilic silicone archtectures via anaerobic thiol - ene chemistry
Keddie, Daniel, Grande, John, Gonzaga, Ferdinand, Brook, Michael, & Dargaville, Tim (2011) Amphiphilic silicone archtectures via anaerobic thiol - ene chemistry. Organic Letters, 13(22), pp. 6006-6009.
Despite broad application, few silicone-based surfactants of known structure or, therefore, surfactancy have been prepared because of an absence of selective routes and instability of silicones to acid and base. Herein the synthesis of a library of explicit silicone-poly(ethylene glycol) (PEG) materials is reported. Pure silicone fragments were generated by the B(C(6)F(5))(3)-catalyzed condensation of alkoxysilanes and vinyl-functionalized hydrosilanes. The resulting pure products were coupled to thiol-terminated PEG materials using photogenerated radicals under anaerobic conditions.
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|Item Type:||Journal Article|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000)|
|Divisions:||Current > Schools > School of Chemistry, Physics & Mechanical Engineering|
Current > QUT Faculties and Divisions > Faculty of Health
Current > Institutes > Institute of Health and Biomedical Innovation
Current > QUT Faculties and Divisions > Science & Engineering Faculty
|Copyright Owner:||Copyright 2011 American Chemical Society|
|Deposited On:||19 Jul 2012 16:28|
|Last Modified:||13 May 2013 16:50|
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