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A Raman spectroscopic study of the uranyl tellurite mineral schmitterite

Frost, Ray L., Cejka, Jiri, Weier, Matt L., & Ayoko, Godwin A. (2006) A Raman spectroscopic study of the uranyl tellurite mineral schmitterite. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 65(3-4), pp. 571-574.

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Abstract

Raman spectra of schmitterite measured at 298 and 77 K are presented and discussed in detail and in part in comparison with published IR spectrum of synthetic schmitterite. U-O bond lengths in uranyls, calculated with the empirical relations RU-O = f[○1(UO2)2+] Å and RU-O = f[○3(UO2)2+] Å, are close to those inferred from the X-ray single crystal structure of synthetic schmitterite and agree also with the data for other natural and synthetic uranyl tellurites.

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ID Code: 5250
Item Type: Journal Article
Additional Information: This is one of a series of papers on the characterisation of uranyl minerals by Raman spectroscopy
Keywords: selenite, tellurite, Raman spectroscopy, U, O bond length, uranyl
DOI: 10.1016/j.saa.2005.12.013
ISSN: 1386-1425
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000)
Divisions: Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright 2006 Elsevier
Copyright Statement: Reproduced in accordance with the copyright policy of the publisher.
Deposited On: 17 Oct 2006
Last Modified: 29 Feb 2012 23:23

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