A Raman spectroscopic study of the uranyl tellurite mineral schmitterite
Frost, Ray L., Cejka, Jiri, Weier, Matt L., & Ayoko, Godwin A. (2006) A Raman spectroscopic study of the uranyl tellurite mineral schmitterite. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 65(3-4), pp. 571-574.
Raman spectra of schmitterite measured at 298 and 77 K are presented and discussed in detail and in part in comparison with published IR spectrum of synthetic schmitterite. U-O bond lengths in uranyls, calculated with the empirical relations RU-O = f[￮1(UO2)2+] Å and RU-O = f[￮3(UO2)2+] Å, are close to those inferred from the X-ray single crystal structure of synthetic schmitterite and agree also with the data for other natural and synthetic uranyl tellurites.
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|Item Type:||Journal Article|
|Additional Information:||This is one of a series of papers on the characterisation of uranyl minerals by Raman spectroscopy|
|Keywords:||selenite, tellurite, Raman spectroscopy, U, O bond length, uranyl|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000)|
|Divisions:||Past > QUT Faculties & Divisions > Faculty of Science and Technology|
|Copyright Owner:||Copyright 2006 Elsevier|
|Copyright Statement:||Reproduced in accordance with the copyright policy of the publisher.|
|Deposited On:||17 Oct 2006|
|Last Modified:||29 Feb 2012 13:23|
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