A Raman spectroscopic study of the uranyl tellurite mineral schmitterite
Frost, Ray L., Cejka, Jiri, Weier, Matt L., & Ayoko, Godwin A. (2006) A Raman spectroscopic study of the uranyl tellurite mineral schmitterite. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 65(3-4), pp. 571-574.
Abstract
Raman spectra of schmitterite measured at 298 and 77 K are presented and discussed in detail and in part in comparison with published IR spectrum of synthetic schmitterite. U-O bond lengths in uranyls, calculated with the empirical relations RU-O = f[○1(UO2)2+] Å and RU-O = f[○3(UO2)2+] Å, are close to those inferred from the X-ray single crystal structure of synthetic schmitterite and agree also with the data for other natural and synthetic uranyl tellurites.
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| ID Code: | 5250 |
|---|---|
| Item Type: | Journal Article |
| Additional Information: | This is one of a series of papers on the characterisation of uranyl minerals by Raman spectroscopy |
| Keywords: | selenite, tellurite, Raman spectroscopy, U, O bond length, uranyl |
| DOI: | 10.1016/j.saa.2005.12.013 |
| ISSN: | 1386-1425 |
| Subjects: | Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) |
| Divisions: | Past > QUT Faculties & Divisions > Faculty of Science and Technology |
| Copyright Owner: | Copyright 2006 Elsevier |
| Copyright Statement: | Reproduced in accordance with the copyright policy of the publisher. |
| Deposited On: | 17 Oct 2006 |
| Last Modified: | 29 Feb 2012 23:23 |
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