The surface-structure sensitivity of dioxygen activation in the anatase-photocatalyzed oxidation reaction

Zhao, Y., Ma, W., Li, Y., Ji, H., Chen, C., Zhu, H., & Zhao, J. (2012) The surface-structure sensitivity of dioxygen activation in the anatase-photocatalyzed oxidation reaction. Angewandte Chemie, 51(13), pp. 3188-3192.

View at publisher


The reaction pathways by which oxygen is incorporated into the substrate in the photocatalytic oxidation of terephthalic acid (TPTA) are vastly different on {001} and {101} facets of an anatase single crystal. This was established by controlling the percentage of {101} and {001} facets, isotopically tracing the origins of the hydroxy group, and studying dioxygen consumption and variance in the concentration of hydroxylation intermediate.

Impact and interest:

50 citations in Scopus
Search Google Scholar™
44 citations in Web of Science®

Citation counts are sourced monthly from Scopus and Web of Science® citation databases.

These databases contain citations from different subsets of available publications and different time periods and thus the citation count from each is usually different. Some works are not in either database and no count is displayed. Scopus includes citations from articles published in 1996 onwards, and Web of Science® generally from 1980 onwards.

Citations counts from the Google Scholar™ indexing service can be viewed at the linked Google Scholar™ search.

ID Code: 52832
Item Type: Journal Article
Refereed: Yes
Keywords: dioxygen activation, hydroxylation, isotopic labeling, photocatalysis, structure-activity relationships, Dioxygens, Hydroxy groups, Oxidation reactions, Photocatalytic oxidations, Reaction pathways, Structure activity relationships, Terephthalic acids, Titanium dioxide
DOI: 10.1002/anie.201107149
ISSN: 1433-7851
Subjects: Australian and New Zealand Standard Research Classification > ENGINEERING (090000)
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Copyright Owner: Copyright 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Deposited On: 07 Aug 2012 23:39
Last Modified: 17 Aug 2012 04:25

Export: EndNote | Dublin Core | BibTeX

Repository Staff Only: item control page