The surface-structure sensitivity of dioxygen activation in the anatase-photocatalyzed oxidation reaction
Zhao, Y., Ma, W., Li, Y., Ji, H., Chen, C., Zhu, H., & Zhao, J. (2012) The surface-structure sensitivity of dioxygen activation in the anatase-photocatalyzed oxidation reaction. Angewandte Chemie, 51(13), pp. 3188-3192.
Abstract
The reaction pathways by which oxygen is incorporated into the substrate in the photocatalytic oxidation of terephthalic acid (TPTA) are vastly different on {001} and {101} facets of an anatase single crystal. This was established by controlling the percentage of {101} and {001} facets, isotopically tracing the origins of the hydroxy group, and studying dioxygen consumption and variance in the concentration of hydroxylation intermediate.
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| ID Code: | 52832 |
|---|---|
| Item Type: | Journal Article |
| Keywords: | dioxygen activation, hydroxylation, isotopic labeling, photocatalysis, structure-activity relationships, Dioxygens, Hydroxy groups, Oxidation reactions, Photocatalytic oxidations, Reaction pathways, Structure activity relationships, Terephthalic acids, Titanium dioxide |
| DOI: | 10.1002/anie.201107149 |
| ISSN: | 1433-7851 |
| Subjects: | Australian and New Zealand Standard Research Classification > ENGINEERING (090000) |
| Divisions: | Current > Schools > School of Chemistry, Physics & Mechanical Engineering Current > QUT Faculties and Divisions > Science & Engineering Faculty |
| Copyright Owner: | Copyright 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| Deposited On: | 08 Aug 2012 09:39 |
| Last Modified: | 17 Aug 2012 14:25 |
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