Meso-Iodo- and meso-iodovinylporphyrins via organopalladium porphyrins and the crystal structure of 5-iodo-10,20-diphenylporphyrin
Atefi, Farzad, Locos, Oliver B., Senge, Mathias O., & Arnold, Dennis P. (2006) Meso-Iodo- and meso-iodovinylporphyrins via organopalladium porphyrins and the crystal structure of 5-iodo-10,20-diphenylporphyrin. Journal of Porphyrins and Phthalocyanines, 10(3-4), pp. 176-185.
![[img]](http://eprints.qut.edu.au/style/images/fileicons/application_pdf.png)
Abstract
The regiospecific halogen exchange reactions of various easily accessible meso-bromoporphyrins to obtain meso-iodoporphyrins, using η1-palladioporphyrins as intermediates, have been investigated. This one-pot methodology allows the isolation of meso-iodoporphyrins in excellent yields with short reaction times. Similarly meso-(2-bromoethenyl)porphyrins can be converted to their iodoethenyl analogues. These iodoporphyrins show great potential as starting materials for various palladium catalysed reactions. The X-ray crystal structure of 5-iodo-10,20-diphenylporphyrin has been determined.
Citations:
Citation countsare sourced monthly from Scopus and Web of Science citation databases.
These databases contain citations from different subsets of available publications and different time periods and thus the citation count from each is usually different. Some works are not in either database and no count is displayed. Scopus includes citations from articles published in 1996 onwards, and Web of Science generally from 1980 onwards.
Citations counts from the Google Scholar™ indexing service can be viewed at the linked Google Scholar™ search.
Full-text downloads:
Full-text downloadsdisplays the total number of times this work’s files (e.g., a PDF) have been downloaded from QUT ePrints as well as the number of downloads in the previous 365 days. The count includes downloads for all files if a work has more than one.
| ID Code: | 5804 |
|---|---|
| Item Type: | Journal Article |
| Additional URLs: | |
| Keywords: | Porphyrinoids, iodination, palladium, organometallic, crystal structure |
| ISSN: | 1088-4246 |
| Subjects: | Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > OTHER CHEMICAL SCIENCES (039900) > Organometallic Chemistry (039904) |
| Divisions: | Past > QUT Faculties & Divisions > Faculty of Science and Technology |
| Copyright Owner: | Copyright 2006 Society of Porphyrins and Phthalocyanines |
| Copyright Statement: | Reproduced in accordance with the copyright policy of the publisher. |
| Deposited On: | 15 Dec 2006 |
| Last Modified: | 29 Feb 2012 23:26 |
Export: EndNote | Dublin Core | BibTeX
Repository Staff Only: item control page